Existent sorbents unlocking and accelerating-net zero industry
Existent is a Canadian cleantech company specializing in advanced adsorbent materials for economical gas separation, including CO₂ capture. Our solutions, built on benchmark metal-organic framework (MOF) sorbents, help industries decarbonize without the complexity of traditional process designs or the risks of legacy technologies that rely on toxic chemicals and produce hazardous waste.
Our portfolio includes proven, user-ready adsorbents. Kilogram-scale supply available in Q2 2026.
The problem
Industrial separations account for 10-15% of global energy consumption and are at the frontlines of global CO₂ emissions, yet decarbonizing these processes has remained technically and economically challenging. For carbon capture, process complexity, high energy demands, and management of toxic adsorbents escalates costs and limits scalability.
Existent’s Breakthrough: CALF-20 Advanced Adsorbent
Existent has commercialized Calgary-Framework 20 (CALF-20), a robust, non-toxic advanced adsorbent uniquely capable of selectively capturing CO₂ even in the presence of water. Traditional solutions absorb water first, requiring costly dehydration steps before CO₂ separation. By eliminating this need, CALF-20 can reduce both capital and operating costs by up to 50%, while delivering high-purity CO₂.
Our technology has been validated through multiple full-scale pilot demonstrations, confirming commercial readiness across diverse applications, including:
- Power generation, combined heat-power
- Petrochemical production
- Electric-arc steel production
- Hydrogen production
- Biogas upgrading
- Cement manufacturing
The materials chemistry behind CALF-20 was highlighted in the 2025 Nobel Prize in Chemistry as the leading example of a metal-organic framework (MOF) with proven industrial utility.
Tech Specs
| Feature | Existent CALF-20 | Zeolites, Molecular Sieves | Activated Carbons | Amine Chemical Adsorbents |
|---|---|---|---|---|
| CO2 Selectivity | High | Moderate to High | Low | High |
| Water Tolerance | Excellent | Excellent | Moderate | High |
| Capture in Wet Gas | Excellent | Minimal | Minimal | High |
| Energy Efficiency of Regeneration | High | Low to Moderate | High | Low |
| Stability (Cycles) | High | Variable | Variable | Low to Moderate |
| Scalability | High | Moderate | High | High |
Everything you need to know about CALF-20 | FAQs
What is CALF-20 in one sentence?
CALF-20, Calgary Framework 20, is a scalable metal-organic framework (MOF) solid sorbent for post-combustion CO2 capture that combines high CO2 selectivity, humidity tolerance, and low regeneration energy in real flue-gas conditions.
Why should a large emitter care about CALF-20 instead of amines?
CALF-20 is designed to avoid the solvent degradation, corrosion, and high regeneration energy burden that make amines expensive to run on wet flue gas.
What is the main business value proposition?
It can lower capture OPEX and CAPEX because is significantly reduces flue gas drying/dehydration (i.e pre-drying needs), which is especially important for gas-fired power, LNG, refining, and industrial heat.
How does humidity affect performance?
CALF-20 actively rejects water, i.e. it is hydrophobic, retains useful CO2 capture capability over a wide humidity range humid. It is most potent up to around 40% RH, but capacity is still maintained even at higher humidity
I’ve heard of CALF-20 variants, do they work?
CALF-20 variants are included in the original CALF-20 patent do take up CO2 but they are not as stable and are unproven industrially. Their stability is a concern, this is why the original form of CALF-20 is scaled and being commercialized.
What regeneration modes are compatible with CALF-20?
CALF-20 can work in temperature swing adsorption (TSA), vacuum swing adsorption (VSA), pressure swing adsorption (PSA), or hybrid swing concepts like VPSA, with the best fit depending on the host process and available waste heat.
How durable is CALF-20?
The literature shows strong cyclic stability, including industrial testing and long-duration demonstrations relevant to plant deployment. Under continuous operation, CALF-20 sorbent will last many years.
Is CALF-20 safe to ship and handle?
CALF-20 is low-risk because it is very insoluble and has low environmental mobility, which supports a simpler handling profile than liquid solvents.
What are the likely operating cost ranges for CALF-20?
Estimates of operating costs are about 18–30 USD/tCO2 captured excluding capital charges.
How does it compare with zeolites?
Compared with zeolites, CALF-20 maintains much better performance in wet gas, where zeolites require upstream drying and lose effective working capacity.
What is the biggest adoption barrier for CALF-20?
The biggest barrier is usually process integration with emission point sources, not the CALF-20 material itself; buyers plant-relevant testing, structured forms, and de-risked cost models. Existent Sorbents Inc. Is commercializing CALF-20 to support adoption and design of carbon capture processes
Can CALF-20 be used in simple fixed-bed equipment?
Pellets, extrudates, granules, and beads of CALF-20 are perfectly suited to constant-contact fixed-bed design reactors. Existent Sorbents Inc. is the exlusive source for these forms of CALF-20.
Does CALF-20 require flue-gas dehydration?
No, that is one of CALF-20’s core advantages; it is designed to tolerate humid gas and therefore reduce or eliminate dehydration demands.
What CALF-20 contactor formats matter most?
Structured pellets, beads, laminates, hollow fiber, and monolith-like forms matter because they determine pressure drop, heat transfer, and cycle speed. Pellets, beads, extrudates, hollow fiber, and monolith-like forms are all available with CALF-20.
What process architecture is most attractive for CALF-20?
For many industrial users, a TSA or hybrid TSA/VSA architecture is attractive because it aligns with low-grade heat and humid flue gas.
Is the kinetics story with CALF-20 good enough for real plants?
Extensive published and industrial work emphasizes rapid uptake and release with CALF-20.
How does it behave in the presence of O2, NOx, SO2, and steam?
CALF-20 is robust under wet flue gas and acid-gas stress conditions, which is central to real post-combustion use.
What plant size can CALF-20 support?
All carbon capture plant sizes are available. Because CALF-20 can be shaped into many forms, it is highly adaptable to a wide array of engineering size scales and engineering types. This is particularly true for pellets, beads, granules, hollow fiber membranes, and monoliths. This forms of CALF-20 are being commercialized by Existent Sorbents Inc. for post-combustion carbon capture and many other types of carbon dioxide (CO2) separations
How does CALF-20 sorbent replacement factor into operations?
Unlike solvent systems, CALF-20 sorbent replacement is not meant to be a routine consumable strategy; the CALF-20 usage model can rely on long cycle life and low attrition.
What is the key engineering risk related to CALF-20?
The key risk is translating CALF-20 into forms that offer low-pressure-drop, thermally manageable, manufacturable structured products. Existent Sorbents Inc. is supplying shaped forms of CALF-20 like beads, pellets, extrudates, hollow fiber membranes, and monoliths that address and abate the engineering risk related to CALF-20.
What evidence would make an EPC comfortable with CALF-20?
Breakthrough curves, cyclic stability, packed-bed performance, and a full heat-and-material-balance model, and scalability of CALF-20 permit inclusion of CALF-20 as a real option.
What is the framework chemistry of CALF-20?
CALF-20 is a zinc triazolate oxalate MOF with the composition [Zn2(1,2,4-triazolate)2(oxalate)].
Why is CALF-20 unusual among physisorbents?
It combines strong CO2 uptake with unexpectedly low water affinity (i.e. hydrophobicity) and CO2 can suppress water adsorption in competitive environments.
What drives CO2 binding in CALF-20?
CO2 binding is dominated by dispersion interactions rather than a classic open-metal-site mechanism.
Why does CALF-20 still work in wet gas?
Its pore geometry and guest-guest competition disfavor water-network formation until higher RH, allowing CO2 to remain competitive.
What happens at high humidity with CALF-20?
The original CALF-20 still uptakes CO2 at high relative humidity, but at lower capacity. CALF-20 variants uptake CO2 at higher relative humidity, but they are not industrially proven.
What synthesis route is used for CALF-20?
The CALF-20 material can be made from commercially available zinc oxalate and triazole precursors.
Why is scalability chemically important?
Many MOFs fail commercialization because they need expensive linkers, metals, or toxic/aprotic solvents, and most often they are not stable; CALF-20 was highlighted as avoiding those traps.
How stable is the framework structurally?
CALF-20 robust to steam, wet flue gas, and repeated cycling, with phase retention under extremely demanding industrial conditions.
What is the most important structure-property lesson?
CALF-20 structural flexibility is key to it’s pore hydrophobicity, and CO2/H2O competitive adsorption, and high CO2 capacity.
Why should governments support CALF-20?
CALF-20 targets one of the hardest decarbonization problems: carbon capture from wet industrial exhaust where alternatives are costly or fragile.
What sectors are most relevant?
Gas-fired power, LNG, refining, petrochemicals, cement production, steam methane reforming, coal, biogas, steel production and other large emitters are near-term targets.
Does CALF-20 help with energy security?
Potentially yes, because it enables emissions reductions without forcing immediate retirement of industrial assets that still provide essential energy and materials. CALF-20 also unlocks climate competitive energy and industrial products.
Is CALF-20 a Canadian technology story?
Yes. CALF-20 is a Canadian-developed material originating from University of Calgary research and later licensed for commercialization. Existent Sorbents Inc. is leading the broad commercialization of CALF-20 so it can become available to all industry and all carbon capture system builders.
Could CALF-20 support Canadian export and jobs policy?
Yes. A scalable CALF-20 sorbent supply chain and capture-system manufacturing base can anchor domestic cleantech jobs and exportable IP.
What is CALF-20's climate relevance?
CALF-20 addresses point-source CO2, which remains one of the largest opportunities for near-term emissions reduction in heavy industry.
Does this technology depend on major subsidies?
Like most first-of-kind breakthrough technologies, CALF-20’s impact is accelerated through policy support early on, but the key selling point is that CALF-20 lowers operating burden versus incumbent approaches.
How should policymakers judge CALF-20's success?
By tons captured, system uptime, energy intensity, and cost per tonne in real industrial deployments, not just by lab uptake numbers.
What is the public-interest case for CALF-20?
Leveraging CALF-20, lower-cost capture at large emitters can reduce emissions while preserving industrial competitiveness and avoiding carbon leakage.
What specific policy levers or government actions would accelerate CALF-20's deployment at national scale?
Several targeted policy actions would be most effective. First, investment tax credits and CCUS tax incentives — similar to the U.S. 45Q credit, which has been boosted to $85 per tonne of CO₂ captured and stored under the Inflation Reduction Act would directly improve project economics for Canadian industrial emitters adopting the technology. Second, procurement and demand-side commitments for low-carbon cement and steel could stimulate early adoption in sectors where CALF-20 has already been demonstrated. Third, expanded federal R&D co-investment in Existent Sorbents Inc. would secure Canadian supply chain leadership before foreign competitors replicate the technology. Fourth, regulatory streamlining for CCUS project approvals, particularly for geological storage in Alberta, would reduce deployment timelines. Finally, given that over 2,000 carbon capture plants are needed globally by 2040, Canada-led international partnerships through Existent Sorbents Inc. to export CALF-20-based materials and packed bed systems to allied nations could turn this University of Calgary innovation into a major clean technology export industry.
What industries can benefit from CALF-20-based carbon capture, and how large is the opportunity?
CALF-20 is applicable across the full breadth of hard-to-abate industrial emitters — sectors where electrification alone cannot eliminate CO₂ emissions. The material’s properties make it relevant to sectors including hydrogen production, cement, chemicals, steel, aluminium, and pulp and paper. These industries collectively account for a significant share of global industrial emissions. In the case of cement production, where two-thirds of emissions arise from chemical reactions related to heating limestone rather than from burning fossil fuels, carbon capture is currently the only scalable solution for reducing emissions. International Energy Agency Over 2,000 carbon capture plants need to be deployed globally by 2040 — the equivalent of commissioning two world-class CO₂ capture plants per week for the next 20 years. CALF-20 is currently the only commercially demonstrated MOF sorbent with the manufacturing pedigree to operate at that pace, making it a strategically vital Canadian asset in the global decarbonization supply chain.
What role has Canadian public funding played in CALF-20's invention, and what is the return on that investment?
CALF-20 is a direct product of sustained public investment in university-based science. The technology was developed over eight years in Dr. Shimizu’s lab at the University of Calgary and drew on collaborations with the University of Alberta’s Dr. Arvind Rajendran, the University of Ottawa’s Dr. Tom Woo.
What is the core IP position around CALF-20?
CALF-20 is covered by patents and licensed fields of use. Existent Sorbents Inc. has been licensed vast majority of rights to CALF-20 from the University of Calgary.
Is CALF-20 itself publicly disclosed?
Yes. The core material was published in Science, so novelty now tends to rest in improvements, formulations, processes, structured forms, and licensing of use cases by Existent Sorbents Inc.
Does the newer high-humidity family create new freedom-to-operate issues?
Potentially yes, because methyl-triazolate variants and humidity-tolerant claims may create additional layer(s) of patent coverage. However, this varients are not industrially stable so their real-world potential is limited versus the original CALF-20.
How important is field-of-use licensing here?
Very important. The public record explicitly notes different licensed fields of use for related CALF-20 patents. The University of Calgary has licensed the vast majority of rights to Existent Sorbents Inc., a University of Calgary spinout that is broadly commercializing CALF-20 for carbon capture systems builders and industrial producers.
Can a new company commercialize CALF-20 at all?
Yes, but it depends on the exact claims, geography, field of use, and whether the company is using licensed IP appropriately from Existent Sorbents Inc.
What diligence questions will investors ask about CALF-20?
They will ask about claim scope, ownership chain, field restrictions, exclusivity, geographic coverage, and whether structured-product or process IP is separate from composition claims, and whether they have paid for the rights from Existent Sorbents Inc.
What policy problem does CALF-20 address?
CALF-20 helps lower the cost and complexity of post-combustion capture from humid industrial sources, which is a major bottleneck in climate policy.
Why is CALF-20 relevant to industrial decarbonization?
Because heavy industry and gas-related infrastructure are difficult to electrify quickly, so carbon capture remains a practical near-term pathway which is economically unlocked by CALF-20.
How should regulations treat CALF-20 sorbent-based capture?
They should recognize that sorbent systems have different energy, safety, and emissions profiles than solvent systems, especially around water and waste handling.
What would a good deployment policy look like for CALF-20?
Supporting CALF-20 for pilots, first-of-a-kind demonstrations, transport and storage infrastructure, and procurement mechanisms that reward verified capture performance.
Does CALF-20 technology fit carbon pricing frameworks?
Yes, because CALF-20 value depends on the avoided emissions cost relative to capture cost and plant-specific carbon price exposure. CALF-20 simplifies and makes carbon capture economical.
What should agencies measure in CALF-20 demos?
Capture rate, durability, energy per tonne, water sensitivity, impurity tolerance, sorbent loss, and real uptime under representative flue gas.
Why does a “wet gas” technology matter for CALF-20 carbon capture policy design?
Because a lot of industrial CO2 streams are wet, and technologies that assume dry gas can look better on paper than they do in practice.
Is CALF-20 more of an enabling technology or a final solution?
It is an enabling sorbent technology platform: useful on its own, but most valuable when integrated into the right contactor, cycle design, and storage chain. The optimal contactor designs like beads, pellets, extrudates, granules, hollow fiber membranes, and monoliths are being commercialized by Existent Sorbents Inc.
What is the main public-policy takeaway for CALF-20?
If governments want deep industrial decarbonization, they need to back capture technologies like CALF-20 that work on real flue gas, not just ideal lab feeds. Innovation funding for Existent Sorbents Inc. which is broadly commercializing CALF-20 can accelerate access to CALF-20 for industry.
How does CALF-20 contribute to Canada's climate commitments and net-zero strategy?
Canada has committed to achieving net-zero emissions by 2050, and carbon capture, utilization, and storage (CCUS) is recognized in federal policy as essential to decarbonizing hard-to-abate industrial sectors. CALF-20 provides a domestically invented, commercially demonstrated pathway to that goal. Multiple large scale deployments proves that the technology can be deployed at industrial facilities today, not in some distant hypothetical future. The results are being watched closely by large CO₂-emitting industries such as Alberta’s energy sector, which is actively searching for commercially viable technologies to remove gases from emissions. Wider deployment could help Canada’s oil sands, natural gas, cement, and chemical producers meet their obligations under carbon pricing frameworks, while simultaneously positioning Canada as a global supplier of the underlying carbon capture material — a clean technology export with no current rival.
What does Existent Sorbents do?
Existent Sorbent’s Inc. has been licensed the vast majority of rights to CALF-20 and is broadly commercializing CALF-20 as beads, pellets, granules, extrudates, hollow fiber membranes, and monoliths so that CALF-20 technology can be accessed by carbon capture systems builders and industry energy and products producers.