Technology
Existent is the only authorized source for CALF-20
CALF-20 is regarded as a leading option for carbon capture due to several key advantages, powered by its ability to preferentially capture (adsorb) CO₂ whiledemonstrating high resistance to moisture interference, and resilience to acid gasses and real-world industrial conditions. With CALF-20, CO₂ sorption suppresses water sorption, a feature unique to CALF-20. This enhances its balanced heat of adsorption allowing for efficient CO₂ uptake without demanding excessive energy inputduring CO2 recovery (desorption).
Feature | Existent CALF-20 | Zeolites, Molecular Sieves | Activated Carbons | Amine Chemical Adsorbents |
CO2 Selectivity | High | Moderate to High | Low | High |
Water Tolerance | Excellent | Excellent | Moderate | High |
Capture in wet gas | Excellent | Minimal | Minimal | High |
Energy Efficiency of Regeneration | High | Low to Moderate | High | Low |
Stability (Cycles) | High | Variable | Variable | Low to Moderate |
Scalability | High | Moderate | High | High |
Technical Highlights:
High Selectivity and Capacity: CALF-20 demonstrates excellent CO₂ adsorption capacity over a wide temperature range and high selectivity for CO₂ over water, which is crucial for post-combustion capture where flue gases are humid.
Moisture Tolerance: Unlike traditional adsorbents such as zeolites and activated carbon, CALF-20 maintains its performance in the presence of water vapor. Beyond co-adsorption of CO2 in water, CALF-20 has a unique ability to suppress water sorption making regeneration easier and giving higher purity CO2 upon release.
Energy-Efficient Regeneration: CALF-20 operates via physisorption, which means CO₂ is captured through weak interactions that require less energy to reverse. This results in lower energy consumption during the regeneration (desorption) process, reducing operational costs.
Stability and Durability: The material exhibits remarkable stability over a wide temperature range (-20 to 99 degrees Celcius) and maintains its structural integrity and adsorption efficiency over multiple cycles, ensuring long-term, reliable performance.
Rapid Cycling and Small Footprint: The synergy between CALF-20’s properties and standard gas separation process designs enables streamlined deployment, allowing carbon capture systems to be more compact and cost-effective.
Scalability and Sustainability: CALF-20 can be responsibly produced at multi-ton scale, aligning with sustainability goals.
CALF-20 is a zinc-based metal-organic framework (MOF) created by researchers at the University of Calgary and developed for efficient carbon dioxide (CO₂) capture in
industrial processes. Learn more about CALF-20 developments and emerging MOF technologies.
What others are saying:
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